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Answer by G. Stefanich for Derived Category of the derived critical locus, is...

These are indeed related. The first thing to know is that they both ``live'' (i.e., sheafify) over the critical locus (this is not saying much if you assume $W$ has isolated critical points, but...

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Derived Category of the derived critical locus, is it the category of Matrix...

Let $W \in \mathbb{C}[x_1, \dots, x_n]=R$ be a polynomial with an isolated critical point at the origin. A Matrix Factorizations for $W$ consists a $\mathbb{Z}/2\mathbb{Z}$-graded finite free...

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